Processes of excitation energy transport in EuPO4 and EuP3O9 nanocrystals

Автор(и)

  • N.V. Kononets Institute for Scintillation Materials, National Academy of Sciences of Ukraine 60 Nauky Ave., Kharkiv 61072, Ukraine
  • V.V. Seminko Institute for Scintillation Materials, National Academy of Sciences of Ukraine 60 Nauky Ave., Kharkiv 61072, Ukraine
  • P.O. Maksimchuk Institute for Scintillation Materials, National Academy of Sciences of Ukraine 60 Nauky Ave., Kharkiv 61072, Ukraine
  • A.V. Aslanov Institute for Scintillation Materials, National Academy of Sciences of Ukraine 60 Nauky Ave., Kharkiv 61072, Ukraine
  • I.I. Bespalova Institute for Scintillation Materials, National Academy of Sciences of Ukraine 60 Nauky Ave., Kharkiv 61072, Ukraine
  • A.A. Masalov Institute for Scintillation Materials, National Academy of Sciences of Ukraine 60 Nauky Ave., Kharkiv 61072, Ukraine
  • Yu.V. Malyukin Institute for Scintillation Materials, National Academy of Sciences of Ukraine 60 Nauky Ave., Kharkiv 61072, Ukraine

DOI:

https://doi.org/10.1063/1.5001311

Ключові слова:

energy transfer, phosphates, luminescence, nanocrystals

Анотація

Processes of excitation energy transport were investigated for EuPO4 and EuP3O9 nanocrystals, in which Eu3+ ions form three- and one-dimensional subsystems, respectively. It was determined that for EuPO4 nanocrystals 5D0 luminescence quenching manifested itself even at low temperatures due to effective phonon-assisted energy migration. At the same time, for EuP3O9 nanocrystals no influence of energy migration on the luminescence quenching was observed in the whole temperature range from 10 to 293 K that can be ascribed to modification of phonon spectra for EuP3O9 nanocrystals as compared to their bulk counterparts.

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Опубліковано

2017-06-19

Як цитувати

(1)
Kononets, N.; Seminko, V.; Maksimchuk, P.; Aslanov, A.; Bespalova, I.; Masalov, A.; Malyukin, Y. Processes of Excitation Energy Transport in EuPO4 and EuP3O9 Nanocrystals. Fiz. Nizk. Temp. 2017, 43, 1252-1256.

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