Sensor properties of nanostructured copper oxide films to ultraviolet radiation

Автор(и)

  • S. I. Petrushenko Technical University of Liberec Studentska, Liberec 46117, Czech Republic

DOI (Low Temperature Physics):


https://doi.org/10.1063/10.0043157

Ключові слова:

нанокомпозити, ультрафіолетові сенсори, тонкі плівки, нанокристали

Анотація

Робота присвячена вивченню сенсорних властивостей нананокомпозитних структур, утворених шляхом атмосферного відпалу мідних плівок. Показано, що відпал мідних плівок товщиною 50–100 нм за температури 280 °C спричиняє утворення нанокомпозитних плівок, що складаються із суміші двох оксидів: CuO та Cu2O. Структури, отримані таким чином, зберігають або навіть збільшують свою дисперсність та демонструють чутливість до ультрафіолетового випромінювання. Було показано, що досліджувані нанокомпозити зворотно знижують свій електричний опір під дією ультрафіолетового випромінювання, тобто можуть бути використані як сенсорні матеріали. Запропоновано декілька механізмів фоточутливості, серед яких найімовірніший полягає у частковому розкладі фази CuO під дією ультрафіолетового випромінювання.

Посилання

L. Zhang, L. Bai, J. Li, Y. Li, X. Li, and L. Guo, “Effect of ablation particles on ultraviolet radiation characteristics in exhaust plume,” J. Quant. Spectrosc. Radiat. Transf. 318, 108952 (2024).https://doi.org/10.1016/j.jqsrt.2024.108952

J. Li, Y. Chen, J. Li, and L. Bai, “Investigation on the ultraviolet spectral radiation characteristics of two-phase flow plume based on OH and alumina particles,” Opt. Exp. 31, 32227 (2023).https://doi.org/10.1364/OE.500476

L. Qin, F. J. Mawignon, M. Hussain, N. K. Ange, S. Lu, M. Hafezi, and G. Dong, “Economic friendly ZnO-based UV sensors using hydrothermal growth: A review,” Materials 14, 4083 (2021).https://doi.org/10.3390/ma14154083

A. F. Abdulrahman, N. M. Abd-Alghafour, and S. M. Ahmed, “Optimization and characterization of SILAR synthesized ZnO nanorods for UV photodetector sensor,” Sens. Actuators A: Phys. 323, 112656 (2021).https://doi.org/10.1016/j.sna.2021.112656

E. Nurfani, L. Nulhakim, D. M. Muhammad, M. Rozana, and W. Astuti, “The enhanced sensing performance of ZnO-based photodetector by Mg doping,” Opt. Mater. 148, 114948 (2024).https://doi.org/10.1016/j.optmat.2024.114948

F. Fabbri and F. Zipoli, “Cathodes for lithium-sulfur batteries,” in Advances in Batteries for Medium and Large-Scale Energy Storage (Woodhead Publishing, 2020), p. 150.https://doi.org/10.1016/B978-0-323-85824-3.00011-7

E. Kianfar, “Advances in nanoelectronics: Carbon nanotubes, graphene, and smart polymers: A review,” Trends Sci. 22, 9843 (2025).https://doi.org/10.48048/tis.2025.9843

S. Mahjoubi, M. Mezyen, G. El Fidha, N. Bitri, and E. Llobet, “The influence of Sn particle incorporation on the photocatalytic activity of sprayed ZnO−SnO2 nanocomposites,” Sci. Rep. 15, 16248 (2025).https://doi.org/10.1038/s41598-025-01370-y

K. Russell, C. A. Kohnke, and J. R. Trelewicz, and A. M. Hodge, “Investigating phase regimes via combinatorial synthesis: A pathway to tailored materials libraries,” Mater. Des. 253, 113881 (2025).https://doi.org/10.1016/j.matdes.2025.113881

N. S. Markin, I. S. Gordeev, H. E. Fu, S. I. Ivannikov, Y. B. Kim, A. Y. Samardak, and A. V. Ognev, “Secondary electron dynamics in core–shell–satellite nanoparticles: A computational strategy for targeted cancer treatment,” Nanoscale 17, 11691 (2025).https://doi.org/10.1039/D5NR00270B

N. Fumeaux, M. Kossairi, J. Bourely, and D. Briand, “Printed ecoresorbable temperature sensors for environmental monitoring,” Micro Nano Eng. 20, 100218 (2023).https://doi.org/10.1016/j.mne.2023.100218

E. Yoo, A. Y. Samardak, Y. S. Jeon, A. S. Samardak, A. V. Ognev, S. V. Komogortsev, and Y. K. Kim, “Composition-driven crystal structure transformation and magnetic properties of electrodeposited Co–W alloy nanowires,” J. Alloys Compd. 843, 155902 (2020).https://doi.org/10.1016/j.jallcom.2020.155902

A. G. Kolesnikov, M. E. Stebliy, A. V. Ognev, A. S. Samardak, A. N. Fedorets, V. S. Plotnikov, and L. A. Chebotkevich, “Enhancement of perpendicular magnetic anisotropy and coercivity in ultrathin Ru/Co/Ru films through the buffer layer engineering,” J. Phys. D: Appl. Phys. 49, 425302 (2016).https://doi.org/10.1088/0022-3727/49/42/425302

S. Dukarov, S. Petrushenko, R. Sukhov, and V. Sukhov, “Nanostructured silver films with a low coefficient of thermal expansion as a promising material for nanoelectronics,” Phys. Status Solidi A 220, 2200664 (2023).https://doi.org/10.1002/pssa.202200664

O. O. Nevgasimov, V. V. Bohomaz, S. I. Petrushenko, and S. V. Dukarov, “Morphology of island structures formed by self-organization processes during melting of lead films,” Mater. Today: Proc. 62, 5787 (2022).https://doi.org/10.1016/j.matpr.2022.03.491

S. V. Dukarov, S. I. Petrushenko, and V. N. Sukhov, “Supercooling during crystallisation and thermal dispergation of thin In-Pb films located between molybdenum layers,” Thin Solid Films 734, 138867 (2021).https://doi.org/10.1016/j.tsf.2021.138867

S. V. Dukarov, S. I. Petrushenko, A. L. Samsonik, and V. N. Sukhov, “Phase diagram of In–Pb alloy in condensed films,” Phys. Status Solidi A 218, 2000455 (2021).https://doi.org/10.1002/pssa.202000455

S. Bogatyrenko, P. Kryshtal, A. Gruszczyński, and A. Kryshtal, “Formation of metastable solid solutions in Bi-Ge films during low-temperature treatment,” Metals 14, 900 (2024).https://doi.org/10.3390/met14080900

A. Kryshtal, S. Bogatyrenko, and O. Khshanovska, “Direct imaging of surface melting on a single sn nanoparticle,” Nano Lett. 23, 6354 (2023).https://doi.org/10.1021/acs.nanolett.3c00943

N. Kumar, S. S. Parui, S. Limbu, D. K. Mahato, N. Tiwari, and R. N. Chauhan, “Structural and optical properties of sol–gel derived CuO and Cu2O nanoparticles,” Mater. Today Proc. 41, 237 (2021).https://doi.org/10.1016/j.matpr.2020.08.800

A. R. Ansari, A. H. Hammad, M. S. Abdel-wahab, M. Shariq, and M. Imran, “Structural, optical and photoluminescence investigations of nanocrystalline CuO thin films at different microwave powers,” Opt. Quant. Electron. 52, 426 (2020).https://doi.org/10.1007/s11082-020-02535-x

S. Petrushenko, S. Dukarov, M. Fijalkowski, and V. Sukhov, “Accelerated recrystallization of nanocrystalline films as a manifestation of the inner size effect of the diffusion coefficient,” Vacuum 226, 113349 (2024).https://doi.org/10.1016/j.vacuum.2024.113349

S. V. Dukarov, S. I. Petrushenko, and V. N. Sukhov, “Inner size effect of temperature coefficient of resistance in Cu, Ag, V and Mo films,” Vacuum 202, 111148 (2022).https://doi.org/10.1016/j.vacuum.2022.111148

K. Mizuno, M. Izaki, K. Murase, T. Shinagawa, M. Chigane, M. Inaba, A. Tasaka, and Y. Awakura, “Structural and electrical characterizations of electrodeposited p-type semiconductor Cu2O films,” J. Electrochem. Soc. 152, C179 (2005).https://doi.org/10.1149/1.1862478

A. Mahmood, F. Tezcan, and G Kardaş, “Photoelectrochemical characteristics of CuO films with different electrodeposition time,” Int. J. Hydrog. Energy 42, 23268 (2017).https://doi.org/10.1016/j.ijhydene.2017.06.003

M. Balık, V. Bulut, and I. Y. Erdogan, “Optical, structural and phase transition properties of Cu2O, CuO, and Cu2O/CuO: Their photoelectrochemical sensor applications,” Int. J. Hydrog. Energy 44, 18744 (2019).https://doi.org/10.1016/j.ijhydene.2018.08.159

F. Bayat and S. Sheibani, “Enhancement of photocatalytic activity of CuO-Cu2O heterostructures through the controlled content of Cu2O,” Mater. Res. Bull. 145, 111561 (2022).https://doi.org/10.1016/j.materresbull.2021.111561

İ. Y. Erdoğan, “The alloying effects on the structural and optical properties of nanocrystalline copper zinc oxide thin films fabricated by spin coating and annealing method,” J. Alloys Compd. 502, 445 (2010).https://doi.org/10.1016/j.jallcom.2010.04.193

N. J. Karazmoudeh, M. Soltanieh, and M. Hasheminiasari, “Structural and photocatalytic properties of undoped and Zn-doped CuO thin films deposited by reactive magnetron sputtering,” J. Alloys Compd. 947, 169564 (2023).https://doi.org/10.1016/j.jallcom.2023.169564

R. Sirirak, P. Chaopanich, A. Prasatkhetragarn, C. Chailuecha, S. Kuimalee, and A. Klinbumrung, “Doping effect of Zn on structural and optical properties of CuO nanostructures prepared by wet chemical precipitation process,” Radiat. Phys. Chem. 190, 109788 (2022).https://doi.org/10.1016/j.radphyschem.2021.109788

Y. Keereeta, R. Sirirak, and A. Klinbumrung, “Revealing effect of cobalt dopant on crystallography and optical characteristics of nanostructured cupric oxide,” Micro Nanostruct. 186, 207757 (2024).https://doi.org/10.1016/j.micrna.2024.207757

E. A. Zeid, I. A. Ibrahem, W. A. Mohamed, and A. M. Ali, “Study the influence of silver and cobalt on the photocatalytic activity of copper oxide nanoparticles for the degradation of methyl orange and real wastewater dyes,” Mater. Res. Exp. 7, 026201 (2020).https://doi.org/10.1088/2053-1591/ab7400

R. Saad, A. M. Ahmed, K. Abdelkarem, M. Zayed, Z. M. Faidey, G. M. Al-Senani, M. Shaban, M. T. Tammam, and H. Hamdy, “SILAR-deposited CuO nanostructured films doped with zinc and sodium for improved CO2 gas detection,” Nanomaterials 13, 2793 (2023).https://doi.org/10.3390/nano13202793

L. Xu, F. Xian, and W. Kuang, “Growth of high quality CuO thin film and investigation of its abnormal luminescence behavior,” Physica B: Condensed Matter 673, 415505 (2024).https://doi.org/10.1016/j.physb.2023.415505

Y. P. Gnatenko, P. M. Bukivskij, V. Y. Yevdokymenko, A. S. Opanasyuk, А. P. Bukivskii, I. G. Vertegel, and O. I. Ovcharenko, “Effect of thermal annealing on the optical properties of 3D-printed nanostructured CuO films for flexible photovoltaic solar cells,” Physica B: Condens. 677, 415737 (2024).https://doi.org/10.1016/j.physb.2024.415737

Ş. Korkmaz, B. Gecici, S. D. Korkmaz, R. Mohammadigharehbagh, S. Pat, S. Özen, V. Şenay, and H. H. Yudar, “Morphology, composition, structure and optical properties of CuO/Cu2O thin films prepared by RF sputtering method,” Vacuum 131, 142 (2016).https://doi.org/10.1016/j.vacuum.2016.06.010

S. Kumar, Bhawna, A. Gupta, R. Kumar, A. Bharti, A. Kumar, and V. Kumar, “New insights into Cu/Cu2O/CuO nanocomposite heterojunction facilitating photocatalytic generation of green fuel and detoxification of organic pollutants,” J. Phys. Chem. C 127, 7095 (2023).https://doi.org/10.1021/acs.jpcc.2c08094

L. M. Peddada, P. P. Cho, S. Dulgaj, R. Annapragada, and P. R. Kanuparthy, “Facile synthesis of green engineered CuO/Cu2O-C nano heterostructures with the controlled Cu2O content for the photodegradation of crystal violet,” Results Opt. 13, 100537 (2023).https://doi.org/10.1016/j.rio.2023.100537

D. Gupta, S. R. Meher, N. Illyaskutty, and Z. C. Alex, “Facile synthesis of Cu2O and CuO nanoparticles and study of their structural, optical and electronic properties,” J. Alloys Compd. 743, 737 (2018).https://doi.org/10.1016/j.jallcom.2018.01.181

D. S. Murali, S. Kumar, R. J. Choudhary, A. D. Wadikar, M. K. Jain, and A. Subrahmanyam, “Synthesis of Cu2O from CuO thin films: Optical and electrical properties,” AIP Adv. 5, 047143 (2015).https://doi.org/10.1063/1.4919323

Y. Wang, P. Miska, D. Pilloud, D. Horwat, F. Mücklich, and J. F. Pierson, “Transmittance enhancement and optical band gap widening of Cu2O thin films after air annealing,” J. Appl. Phys. 115, 073505 (2014).https://doi.org/10.1063/1.4865957

Q. Huang, J. Li, and X. Bi, “The improvement of hole transport property and optical band gap for amorphous Cu2O films,” J. Alloys Compd. 647, 585 (2015).https://doi.org/10.1016/j.jallcom.2015.06.147

M. S. Jo, H. J. Song, B. J. Kim, Y. K. Shin, S. H. Kim, X. Tian, S. M. Kim, M. H. Seo, and J. B. Yoon, “Aligned CuO nanowire array for a high performance visible light photodetector,” Sci. Rep. 12, 2284 (2022).https://doi.org/10.1038/s41598-022-06031-y

S. K. Kajli, D. Ray, and S. C. Roy, “Efficient UV–visible photodetector based on single CuO/Cu2O core-shell nanowire,” J. Alloys Compd. 895, 162546 (2022).https://doi.org/10.1016/j.jallcom.2021.162546

R. Siddaramaiah, V. K. S. Yadav, A. Pal, and R. P. Palathinkal, “High-performance CuO nanowire printed devices for visible light sensing and switching characteristics,” Mater. Lett. 320, 132300 (2022).https://doi.org/10.1016/j.matlet.2022.132300

Y. H. Ko, G. Nagaraju, S. H. Lee, and J. S. Yu, “Facile preparation and optoelectronic properties of CuO nanowires for violet light sensing,” Mater. Lett. 117, 217 (2014).https://doi.org/10.1016/j.matlet.2013.11.119

D. Mahana, R. Yadav, P. Singh, S. Husale, and S. K. Muthusamy, “Photo-sensing characteristics of CuO thin films synthesized by thermal oxidation of Cu metal films,” Opt. Mater. 148, 114903 (2024).https://doi.org/10.1016/j.optmat.2024.114903

A. Tripathi, T. Dixit, J. Agrawal, and V. Singh, “Bandgap engineering in CuO nanostructures: Dual-band, broadband, and UV-C photodetectors,” Appl. Phys. Lett. 116, 111102 (2020).https://doi.org/10.1063/1.5128494

S. Y. Lee, N. Mettlach, N. Nguyen, Y. M. Sun, and J. M. White, “Copper oxide reduction through vacuum annealing,” Appl. Surf. Sci. 206, 102 (2003).https://doi.org/10.1016/S0169-4332(02)01239-4

R. Jayakrishnan, A. S. Kurian, V. G. Nair, and M. R. Joseph, “Effect of vacuum annealing on the photoconductivity of CuO thin films grown using sequential ionic layer adsorption reaction,” Mater. Chem. Phys. 180, 149 (2016).https://doi.org/10.1016/j.matchemphys.2016.05.055

Y. Maimaiti, M. Nolan, and S. D. Elliott, “Reduction mechanisms of the CuO (111) surface through surface oxygen vacancy formation and hydrogen adsorption,” PCCP 16, 3036 (2014).https://doi.org/10.1039/c3cp53991a

C. Guillén and J. Herrero, “Single-phase Cu2O and CuO thin films obtained by low-temperature oxidation processes,” J. Alloys Compd. 737, 718 (2018).https://doi.org/10.1016/j.jallcom.2017.12.174

A. Sharma, B. Bhattacharyya, A. K. Srivastava, T. D. Senguttuvan, and S. Husale, “High performance broadband photodetector using fabricated nanowires of bismuth selenide,” Sci. Rep. 6, 19138 (2016).https://doi.org/10.1038/srep19138

J. Wu, H. Li, Y. Liu, and C. Xie, “Photoconductivity and trap-related decay in porous TiO2/ZnO nanocomposites,” J. Appl. Phys. 110, 123513 (2011).https://doi.org/10.1063/1.3662954

R. H. Bube, Photoelectronic Properties of Semiconductors (Cambridge University Press, Cambridge, 1992). ISBN 0-521-40681-1.

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2026-02-25

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S. I. Petrushenko, Sensor properties of nanostructured copper oxide films to ultraviolet radiation, Low Temp. Phys. 52, (2026) [Fiz. Nyzk. Temp. 52, 516–526, (2026)] DOI: https://doi.org/10.1063/10.0043157.

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