Positron annihilation characterization of free volume in micro- and macro-modified Cu0.4Co0.4Ni0.4Mn1.8O4 ceramics
DOI (Low Temperature Physics):
https://doi.org/10.1063/1.4959021%20Ключові слова:
ceramics, free volume, nanopores, positron trapping, positronium decaying.Анотація
Free volume and pore size distribution size in functional micro and macro-micro-modified Cu0.4Co0.4Ni0.4Mn1.8O4 ceramics are characterized by positron annihilation lifetime spectroscopy in comparison with Hg-porosimetry and scanning electron microscopy technique. Positron annihilation results are interpreted in terms of model implication positron trapping and ortho-positronium decaying. It is shown that free volume of positron traps are the same type for macro and micro modified Cu0.4Co0.4Ni0.4Mn1.8O4 ceramics. Classic Tao-Eldrup model in spherical approximation is used to calculation of the size of nanopores smaller than 2 nm using the ortho-positronium lifetime.
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2016-05-18
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H. Klym, A. Ingram, O. Shpotyuk, I. Hadzaman, V. Solntsev, O. Hotra, and A.I. Popov, Positron annihilation characterization of free volume in micro- and macro-modified Cu0.4Co0.4Ni0.4Mn1.8O4 ceramics, Low Temp. Phys. 42, (2016) [Fiz. Nizk. Temp. 42, 764-769, (2016)] DOI: https://doi.org/10.1063/1.4959021 .
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