Heat transfer by low-frequency phonons and "diffusive" modes in cryocrystal solutions: the Kr–Xe system

Low-Temperature Thermodynamics and Structure

Анотація

The temperature and volume dependences of the thermal conductivity of the Kr_1–x Xe_x solid solution are analyzed in a model in which heat is transferred by low-frequency phonons; above the phonon mobility edge this is done by "diffusive" modes migrating randomly from site to site. The phonon mobility edge w₀ is determined from the condition that the phonon mean free path limited by umklapp processes and scattering on point defects cannot be smaller than one-half the phonon wavelength. The Bridgman coefficientg g = - (¶ ln / L ¶ ln V)_T is the weighted mean over these modes, whose volume dependences differ strongly. It is shown that the amount of heat transferred by the "diffusive" modes above 100 K is quite large even in pure Kr and it increases with rising temperature and impurity concentration.